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anteiso-branched-chain fatty acid biosynthesis

State Icon Reaction EC-Number Confidence maximal confidence score from EnzymeDetector
(14S)-14-methylhexadecanoyl-[acp] + H2O <=> (14S)-14-methylhexadecanoate + [acyl-carrier_protein] + H+ 3.1.2.14 oleoyl-[acyl-carrier-protein] hydrolase
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(4S,3R)-3-hydroxy-4-methylhexanoyl-[acp] <=> (2E,4S)-4-methylhex-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase
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(14S)-14-methylhexadecanoyl-[acp] + NAD+ <=> (2E,14S)-14-methylhexadec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)
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(14S)-14-methylhexadecanoyl-[acp] + NADP+ <=> (2E,14S)-14-methylhexadec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
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(3R,6S)-3-hydroxy-6-methyloctanoyl-[acp] + NADP+ <=> (6S)-6-methyl-3-oxooctanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase
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(12S)-12-methyltetradecanoyl-[acp] + H2O <=> (12S)-12-methyltetradecanoate + [acyl-carrier_protein] + H+ 3.1.2.14 oleoyl-[acyl-carrier-protein] hydrolase
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(6S)-6-methyloctanoyl-[acp] + NADP+ <=> (2E,6S)-6-methyloct-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
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(3R,10S)-3-hydroxy-10-methyldodecanoyl-[acp] + NADP+ <=> (10S)-10-methyl-3-oxododecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase
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(3R,14S)-3-hydroxy-14-methylhexadecanoyl-[acp] <=> (2E,14S)-14-methylhexadec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase
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(3R,6S)-3-hydroxy-6-methyloctanoyl-[acp] <=> (2E,6S)-6-methyloct-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase
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(10S)-10-methyldodecanoyl-[acp] + NADP+ <=> (2E,10S)-10-methyldodec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
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(3R,12S)-3-hydroxy-12-methyltetradecanoyl-[acp] <=> (2E,12S)-12-methyltetradec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase
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(10S)-10-methyldodecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (12S)-12-methyl-3-oxotetradecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II
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(12S)-12-methyltetradecanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (14S)-14-methyl-3-oxohexadecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II
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(3R,8S)-3-hydroxy-8-methyldecanoyl-[acp] <=> (2E,8S)-8-methyldec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase
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(10S)-10-methyldodecanoyl-[acp] + NAD+ <=> (2E,10S)-10-methyldodec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)
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(4S)-4-methylhexanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (6S)-6-methyl-3-oxooctanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II
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(3R,8S)-3-hydroxy-8-methyldecanoyl-[acp] + NADP+ <=> (8S)-8-methyl-3-oxodecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase
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(3R,10S)-3-hydroxy-10-methyldodecanoyl-[acp] <=> (2E,10S)-10-methyldodec-2-enoyl-[acp] + H2O 4.2.1.59 3-hydroxyacyl-[acyl-carrier-protein] dehydratase
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(8S)-8-methyldecanoyl-[acyl-carrier_protein] + NADP+ <=> (2E,8S)-8-methyldec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
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(12S)-12-methyltetradecanoyl-[acp] + NADP+ <=> (2E,12S)-12-methyltetradec-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
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(4S,3R)-3-hydroxy-4-methylhexanoyl-[acp] + NADP+ <=> (4S)-4-methyl-3-oxohhexanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase
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(4S)-4-methylhexanoyl-[acp] + NAD+ <=> (2E,4S)-4-methylhex-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)
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(8S)-8-methyldecanoyl-[acyl-carrier_protein] + NAD+ <=> (2E,8S)-8-methyldec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)
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(3R,14S)-3-hydroxy-14-methylhexadecanoyl-[acp] + NADP+ <=> (14S)-14-methyl-3-oxohexadecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase
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(3R,12S)-3-hydroxy-12-methyltetradecanoyl-[acp] + NADP+ <=> (12S)-12-methyl-3-oxotetradecanoyl-[acp] + NADPH + H+ 1.1.1.100 3-oxoacyl-[acyl-carrier-protein] reductase
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(6S)-6-methyloctanoyl-[acp] + NAD+ <=> (2E,6S)-6-methyloct-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)
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L-isoleucine + 2-oxoglutarate <=> L-glutamate + (S)-3-methyl-2-oxopentanoate 2.6.1.42 branched-chain-amino-acid transaminase
2.6.1.67 2-aminohexanoate transaminase
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(8S)-8-methyldecanoyl-[acyl-carrier_protein] + malonyl-[acyl-carrier_protein] + H+ <=> (10S)-10-methyl-3-oxododecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II
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(4S)-4-methylhexanoyl-[acp] + NADP+ <=> (2E,4S)-4-methylhex-2-enoyl-[acp] + NADPH + H+ 1.3.1.10 enoyl-[acyl-carrier-protein] reductase (NADPH, Si-specific)
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(S)-2-methylbutanoyl-CoA + malonyl-[acyl-carrier_protein] + H+ <=> (4S)-4-methyl-3-oxohhexanoyl-[acp] + CoA + CO2 2.3.1.dr
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(6S)-6-methyloctanoyl-[acp] + malonyl-[acyl-carrier_protein] + H+ <=> (8S)-8-methyl-3-oxodecanoyl-[acp] + CO2 + [acyl-carrier_protein] 2.3.1.179 beta-ketoacyl-[acyl-carrier-protein] synthase II
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(12S)-12-methyltetradecanoyl-[acp] + NAD+ <=> (2E,12S)-12-methyltetradec-2-enoyl-[acp] + NADH + H+ 1.3.1.9 enoyl-[acyl-carrier-protein] reductase (NADH)
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(S)-3-methyl-2-oxopentanoate + NAD+ + CoA <=> (S)-2-methylbutanoyl-CoA + NADH + CO2 1.2.1.25 branched-chain alpha-keto acid dehydrogenase system
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